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| Study on Preparation and Properties of Nanocellulose-Polymerizable Deep Eutectic Solvents Ionic Conductive Elastomer |
| Received:March 07, 2023 |
| DOI:10.11980/j.issn.0254-508X.2023.05.005 |
| Key Words:ionic conductive elastomer polymerizable deep eutectic solvents cellulose nanofibril phytic acid |
| Fund Project:国家自然科学基金项目(32071715)。 |
| Author Name | Affiliation | Postcode | | NING Chenxi | School of Light Industry Science and Engineering, Tianjin University of Science and Technology, Tianjin, 300457 State Key Lab of Biobased Fiber Manufacturing Technology, Tianjin University of Science and Technology, Tianjin, 300457 | 300457 | | ZHANG Xiao | School of Light Industry Science and Engineering, Tianjin University of Science and Technology, Tianjin, 300457 State Key Lab of Biobased Fiber Manufacturing Technology, Tianjin University of Science and Technology, Tianjin, 300457 | 300457 | | JIANG Chuang | School of Light Industry Science and Engineering, Tianjin University of Science and Technology, Tianjin, 300457 State Key Lab of Biobased Fiber Manufacturing Technology, Tianjin University of Science and Technology, Tianjin, 300457 | 300457 | | LIU Wei* | School of Light Industry Science and Engineering, Tianjin University of Science and Technology, Tianjin, 300457 State Key Lab of Biobased Fiber Manufacturing Technology, Tianjin University of Science and Technology, Tianjin, 300457 | 300457 | | SUN Haoxuan | School of Light Industry Science and Engineering, Tianjin University of Science and Technology, Tianjin, 300457 State Key Lab of Biobased Fiber Manufacturing Technology, Tianjin University of Science and Technology, Tianjin, 300457 | 300457 | | HOU Qingxi | School of Light Industry Science and Engineering, Tianjin University of Science and Technology, Tianjin, 300457 State Key Lab of Biobased Fiber Manufacturing Technology, Tianjin University of Science and Technology, Tianjin, 300457 | 300457 |
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| Abstract:In this study, polymerizable deep eutectic solvents (PDES) synthesized from acrylic acid and choline chloride was combined with cellulose nanofibril (CNF) aerogels by UV-initiated in situ polymerization, and phytic acid was introduced to enhance the bonding between CNF and PDES. The ionic conductive elastomers containing abundant covalent bonds and non-covalent bonds (hydrogen bonds) were prepared, and their properties were tested by a variety of modern instruments. The results showed that the ionic conductive elastomers had obvious advantages in mechanical properties (stress of 0.38 MPa and strain of 1378%), thermal stability, frost resistance, ionic conductivity (ionic conductivity up to 3.9 mS/cm) and UV shielding, and had certain fatigue resistance and elasticity. And the flexible strain sensor based on the assembly showed rapid, stable and reversible signal responsed to human movement. |
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