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Study on Oil-absorbing Hydrophobic Fiber Reinforced Starch-Based Absorbent Materials
Received:June 04, 2021  
DOI:10.11980/j.issn.0254-508X.2021.12.007
Key Words:corn starch  hydrophobic modification  foam material  coniferous wood fiber  adsorption
Fund Project:陕西省咸阳市科学技术研究计划项目(2017k02-25);大学生创新创业训练计划项目(S202110708107X)。
Author NameAffiliationPostcode
CAI Xue College of Bioresources Chemical and Materials Engineering Shaanxi Province Key Lab of Papermaking Technology and Specialty Paper Development China National Light Industry Key Lab of Paper based Functional Materials Key Laboratory of Auxiliary Chemistry & Technology for Chemical Industry Ministry of Education National Demonstration Center for Experimental Light Chemistry Engineering Education Shaanxi University of Science & Technology Xi’an Shaanxi Province 710021 710021
ZHANG Yuhao College of Bioresources Chemical and Materials Engineering Shaanxi Province Key Lab of Papermaking Technology and Specialty Paper Development China National Light Industry Key Lab of Paper based Functional Materials Key Laboratory of Auxiliary Chemistry & Technology for Chemical Industry Ministry of Education National Demonstration Center for Experimental Light Chemistry Engineering Education Shaanxi University of Science & Technology Xi’an Shaanxi Province 710021 710021
YIN Xuefeng College of Bioresources Chemical and Materials Engineering Shaanxi Province Key Lab of Papermaking Technology and Specialty Paper Development China National Light Industry Key Lab of Paper based Functional Materials Key Laboratory of Auxiliary Chemistry & Technology for Chemical Industry Ministry of Education National Demonstration Center for Experimental Light Chemistry Engineering Education Shaanxi University of Science & Technology Xi’an Shaanxi Province 710021 710021
WANG Ruichen College of Bioresources Chemical and Materials Engineering Shaanxi Province Key Lab of Papermaking Technology and Specialty Paper Development China National Light Industry Key Lab of Paper based Functional Materials Key Laboratory of Auxiliary Chemistry & Technology for Chemical Industry Ministry of Education National Demonstration Center for Experimental Light Chemistry Engineering Education Shaanxi University of Science & Technology Xi’an Shaanxi Province 710021 710021
LIN Jiacheng College of Bioresources Chemical and Materials Engineering Shaanxi Province Key Lab of Papermaking Technology and Specialty Paper Development China National Light Industry Key Lab of Paper based Functional Materials Key Laboratory of Auxiliary Chemistry & Technology for Chemical Industry Ministry of Education National Demonstration Center for Experimental Light Chemistry Engineering Education Shaanxi University of Science & Technology Xi’an Shaanxi Province 710021 710021
LIN Tao* College of Bioresources Chemical and Materials Engineering Shaanxi Province Key Lab of Papermaking Technology and Specialty Paper Development China National Light Industry Key Lab of Paper based Functional Materials Key Laboratory of Auxiliary Chemistry & Technology for Chemical Industry Ministry of Education National Demonstration Center for Experimental Light Chemistry Engineering Education Shaanxi University of Science & Technology Xi’an Shaanxi Province 710021 710021
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Abstract:In this study, fiber reinforced starch-based foam materials were prepared with corn starch as raw material and pretreated softwood fibers as reinforcement. The results showed that the mechanical properties and pore structure of starch-based foam materials were greatly improved after adding a small amount of softwood fibers. When the starch content was 4.5% and the softwood fibers content was 1.5%, the compressive strength of the material reached the maximum of 4.66 MPa. At this time, the porosity of the material was 88% and the density was 0.13 g/cm3. The adsorption results showed that the starch-based foam materials mainly absorbed water. Then, the corn starch was hydrophobic modified by esterification, and the fiber reinforced starch-based foam materials with hydrophobic modification were prepared with softwood fibers as reinforcement. When the dosage of hydrochloric acid was same, the dosage of stearic acid was 6 g, the tensile strength reached the maximum of 0.25 MPa. When the dosage of stearic acid was 4 g, the compressive strength reached the maximum of 4.76 MPa. Thus, compared to the materials before modification, both the mechanical properties and hydrophobicity of hydrophobic modified materials were improved. The oil-water ratio of adsorption was also improved, so that the materials had a certain lipophilicity.
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