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Study on Photocatalytic Treatment of Papermaking Effluent by CF Nano-titanium Dioxide Photocatalyst
  
DOI:10.11980/j.issn.0254-508X.2016.01.006
Key Words:cerium  fluorine  nano-TiO2  photocatalytic  paper effluent
Author NameAffiliation
刘 苗1 1.陕西科技大学轻工与能源学院,陕西西安710021 
杨 军1 1.陕西科技大学轻工与能源学院,陕西西安710021 
高玉刚1 1.陕西科技大学轻工与能源学院,陕西西安710021 
刘保健2 2.陕西科技大学轻化工助剂化学与技术教育部重点实验室,陕西西安,710021 
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Abstract:The CF nano- TiO2 photocatalyst(nano- TiO2 doped with Ce、F)was prepared by using TiCl4、Ce(NO3)4 and NH4F as raw material and modified sol-gel method, crystal structure and optical absorption property of the CF photocatalyst were characterized by XRD and UV-vis DRS. The results indicated that the CF photocatalyst belonged to anatase structure and strong absorption in UV spectrum(≦400 nm). CODCr and chroma removal rate of the waste water from the second clarinet of a paper mill’s effluent treatment plant reached 88.9% and 95.2% respectively when the waste water was treated with the CF photocatalyst under the following conditions: pH value 4, dosage of catalyst 0.8 g/L and light radiation time 40 min.
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