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Preparation of Cationic Starch Immobilized by β-Cyclodextrin and Its Application in Antibacterial Paper
  
DOI:10.11980/j.issn.0254-508X.2014.02.003
Key Words:cationic starch  β-cyclodextrin  immobilization  antibacterial effect  mechanical properties
Fund Project:国家自然科学基金项目(31200457)和中央高校基本科研业务费(2013ZZ0072)专项资金资助。
Author NameAffiliation
董 超1 1.华南理工大学制浆造纸工程国家重点实验室,广东广州510640 
叶 迎1 1.华南理工大学制浆造纸工程国家重点实验室,广东广州510640 
钱丽颖1,* 1.华南理工大学制浆造纸工程国家重点实验室,广东广州510640 
何北海1 1.华南理工大学制浆造纸工程国家重点实验室,广东广州510640 
肖惠宁2 2.University of New Brunswick, Fredericton, New Brunswick, CanadaE3B5A3 
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Abstract:The preparation of cationic starch immobilized by β-cyclodextrin (β-CD-CS) and its application in papermaking after forming inclusion complexes with ciprofloxacin hydrochloride (CipHCl) were studied. The results showed that the optimal conditions of synthesizing β-CD-CS were as follows: the molar ratio of epichlorohydrin to β-CD was 5∶1 and the reaction temperature was at 40℃. With the amount of β-CD-CS used for forming the inclusion complex increasing, the tensile strength, tear strength and bursting strength of the paper sheets increased firstly and then decreased. It also showed that the antibacterial effect of the paper sheets containing the inclusion complexes was excellent and increased with the higher adding amount of the inclusion complexes. When the adding amount of the inclusion complexes was 2.5%, the inhibition zones of the paper sheets against E.coli and S.aureus were 16.9 mm and 16.3 mm respectively.
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