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Study on the Preparation of Cellulose Nanocrystal-based Circularly Polarized Fluorescent Film and Its Stimulus-responsive Properties
Received:January 11, 2026  Revised:February 12, 2026
DOI:10.11980/j.issn.0254-508X.2026.07.004
Key Words:cellulose nanocrystals  curcumin  circularly polarized fluorescent film  stimulus-responsive properties
Author NameAffiliationPostcode
Li Xinxin* 1China Tobacco Hubei Industrial Co., Ltd., Wuhan, Hubei Province, 430040
2China Tobacco Hubei Industrial of Cigarette Material Co., Ltd., Wuhan, Hubei Province, 430040 
430040
Liu Qiang* 1China Tobacco Hubei Industrial Co., Ltd., Wuhan, Hubei Province, 430040
2China Tobacco Hubei Industrial of Cigarette Material Co., Ltd., Wuhan, Hubei Province, 430040 
430040
Chen Congxin 1China Tobacco Hubei Industrial Co., Ltd., Wuhan, Hubei Province, 430040
2China Tobacco Hubei Industrial of Cigarette Material Co., Ltd., Wuhan, Hubei Province, 430040 
430040
Li Lixin 1China Tobacco Hubei Industrial Co., Ltd., Wuhan, Hubei Province, 430040
2China Tobacco Hubei Industrial of Cigarette Material Co., Ltd., Wuhan, Hubei Province, 430040 
430040
Ye Peiyao 1China Tobacco Hubei Industrial Co., Ltd., Wuhan, Hubei Province, 430040
2China Tobacco Hubei Industrial of Cigarette Material Co., Ltd., Wuhan, Hubei Province, 430040 
430040
Meng Yahui* 3School of Environmental and Nature Resources, Zhejiang University of Science and Technology, Hangzhou, Zhejiang Province, 310023 310023
Jia Zhixin 3School of Environmental and Nature Resources, Zhejiang University of Science and Technology, Hangzhou, Zhejiang Province, 310023
4Zhejiang Huafeng Paper Technology Co., Ltd., Huzhou, Zhejiang Province, 313300 
313300
Yang Jiaxi 4Zhejiang Huafeng Paper Technology Co., Ltd., Huzhou, Zhejiang Province, 313300 313300
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Abstract:A multi-stimulus-responsive film with structural coloration, fluorescence, and circularly polarized luminescence (CPL) performance was fabricated through the co-assembly of cellulose nanocrystals (CNC), curcumin (Cur), and choline chloride/glycerin deep eutectic solvent (DES). The structure, mechanical properties, optical properties, and stimulus-responsive behaviors of the prepared CNC/Cur/DES film were systematically investigated. The results showed that the incorporation of DES effectively regulated the chiral nematic structure of CNC, endowing the film with good flexibility (fracture strain of (1.77±0.31)%) and CPL performance. The CNC/Cur/DES film enabled the synergistic output of structural color and fluorescence signals and exhibited distinct optical responses to various external stimuli, including pH, ethanol, and Fe3+, demonstrating excellent visual recognition capability.
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