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Study on the Cooling Performance of Paper-based Composites Containing Phase Change Microcapsules
Received:September 16, 2025  Revised:October 09, 2025
DOI:10.11980/j.issn.0254-508X.2026.04.007
Key Words:paper-based composites  phase change microcapsule (PCM)  coating  cooling effect
Fund Project:制浆造纸国家工程实验室基金项目(ZZY2023ZZXT02)。
Author NameAffiliationPostcode
ZHANG Ying* 1Paper Industry Productivity Promotion Center, Quzhou, Zhejiang Province, 324400
3School of Chemistry, Jilin Normal University, Siping, Jilin Province,136000 
136000
ZHAO Lijun* 1Paper Industry Productivity Promotion Center, Quzhou, Zhejiang Province, 324400 324400
CHAO Lumen 2China National Pulp and Paper Research Institute Co., Ltd., Beijing, 100102 100102
YANG Yang 2China National Pulp and Paper Research Institute Co., Ltd., Beijing, 100102 100102
HUANG Jianbo 2China National Pulp and Paper Research Institute Co., Ltd., Beijing, 100102 100102
LI Hongkai 1Paper Industry Productivity Promotion Center, Quzhou, Zhejiang Province, 324400 324400
LIU Wen 1Paper Industry Productivity Promotion Center, Quzhou, Zhejiang Province, 324400
2China National Pulp and Paper Research Institute Co., Ltd., Beijing, 100102 
100102
WANG Songpeng 1Paper Industry Productivity Promotion Center, Quzhou, Zhejiang Province, 324400 324400
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Abstract:In this study, a novel paper-based composites containing phase change microcapsules (C-PCM) was fabricated for the cooling segment of heat not burn (HNB) cigarettes. Using paper as the substrate, a coating solution was prepared by dispersing phase change microcapsules (PCM) in a polyvinyl alcohol (PVA) solution, which was then applied onto the paper. Through optimization of PVA concentration, phase change temperature, and coating parameters, the coating solution optimal preparation conditions were determined as: PVA solution mass fraction was 5%, PCM phase change temperature was 45 ℃, coating solution solid content was 20%. The C-PCM prepared under this condition reduced the maximum temperature of the cigarette filter to 37.4 ℃, significantly outperforming commercially available HNB cigarette filters. The phase change enthalpy of C-PCM reached 120.3 J/g at this coating condition, confirming excellent heat absorption capability. Additionally, C-PCM exhibits favorable tensile index (57.4 N·m/g), hydrophilicity (water contact angle 44.2°), and oil resistance. When maintaining the cooling performance of C-PCM as much as possible, adding an appropriate amount of CaCO3 thermal conductive filler could replace an appropriate amount of phase change microcapsules to save costs.
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