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Preparation of Nanocellulose-based Dyes and Their Coloring Performance on Paper
Received:May 31, 2025  Revised:August 02, 2025
DOI:10.11980/j.issn.0254-508X.2025.11.003
Key Words:nanocellulose  dyes  paper  chromaticity values  prediction model
Fund Project:山东省高等学校青年创新团队项目(2023KJ330);全国重点实验室建设重大科研专项(2025ZDGZ02)。
Author NameAffiliationPostcode
FU Bin* State Key Lab of Green Papermaking and Resource Recycling, Qilu University of Technology (Shandong Academy of Sciences), Ji’nan, Shandong Province, 250353 250353
PEI Lihua Shandong Dingan Testing Co., Ltd., Ji’nan, Shandong Province, 250000 250000
ZHOU Rong State Key Lab of Green Papermaking and Resource Recycling, Qilu University of Technology (Shandong Academy of Sciences), Ji’nan, Shandong Province, 250353 250353
ZHANG Bo State Key Lab of Green Papermaking and Resource Recycling, Qilu University of Technology (Shandong Academy of Sciences), Ji’nan, Shandong Province, 250353 250353
ZHANG Rongjun State Key Lab of Green Papermaking and Resource Recycling, Qilu University of Technology (Shandong Academy of Sciences), Ji’nan, Shandong Province, 250353 250353
WANG Shengdan* State Key Lab of Green Papermaking and Resource Recycling, Qilu University of Technology (Shandong Academy of Sciences), Ji’nan, Shandong Province, 250353 250353
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Abstract:Nanocellulose-based dye (ND) was prepared by bio-mechanical method using bleached softwood pulp as raw material. The dyeing performance of ND on paper was investigated. Furthermore the influence of ND addition amount on the chromaticity values of paper was analyzed, and a predictive model for dyeing effects was established. The results showed that the prepared ND with a diameter of approximately 10~25 nm and could be uniformly dispersed in water. Paper dyed via internal sizing exhibited uniform color, and ND in the wastewater settled naturally after 15 h of standing. After being rubbed 1 000 times with a 10 N force, the color difference (∆E) of the dyed paper was 0.54. The prediction model achieved the R² of 0.997, enabling it to accurately predict the impact of different additive amounts on the chromaticity values of paper.
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