本文二维码信息
二维码(扫一下试试看!)
Construction of Cellulose Films with High Wet-stability Based on Dissolving-co-crosslinking Cellulose in AlCl3/ZnCl2 Aqueous System
Received:March 06, 2025  Revised:April 28, 2025
DOI:10.11980/j.issn.0254-508X.2025.10.007
Key Words:cellulose film  dissolving-co-crosslinking  wet stability  food preservation
Fund Project:江苏省市场监管局科技计划项目(KJ2026097)。
Author NameAffiliationPostcode
WU Bin* Huai’an Product Quality Supervision and Inspection Center, Huai’an , Jiangsu Province, 223001
College of Light Industry and Food Technology, Nanjing Forestry University, Nanjing, Jiangsu Province, 210037 
210037
LI Bin Huai’an Product Quality Supervision and Inspection Center, Huai’an , Jiangsu Province, 223001 223001
LIANG Tingting Huai’an Product Quality Supervision and Inspection Center, Huai’an , Jiangsu Province, 223001 223001
LI Xianchun College of Light Industry and Food Technology, Nanjing Forestry University, Nanjing, Jiangsu Province, 210037 210037
LI Xin College of Light Industry and Food Technology, Nanjing Forestry University, Nanjing, Jiangsu Province, 210037 210037
WANG Zhiguo* College of Light Industry and Food Technology, Nanjing Forestry University, Nanjing, Jiangsu Province, 210037 210037
Hits: 2329
Download times: 711
Abstract:In this study, AlCl3/ZnC2/H2O was used as solvent, 1,4-butanediol diglycidyl ether (BDDE) was introduced as crosslinking agent, and bleached eucalyptus as the cellulose raw material. Cellulose was dissolved and crosslinked at room temperature to prepare the cellulose film. When the amount of cellulose and BDDE are 1.5% and 1.0%, respectively, the film had the advantages of high strength, high wet stability, high transparency, and biodegradability. Its light transmittance could reach 90%. The stress-strain energies of the obtained cellulose films reached 141.0 MPa and 19.7%, respectively. Even after soaking in water for 24 h, the wet stress and strain could reach 34.7 MPa and 67.3%. After being soaked in water for 7 days, it could still maintain a stable shape, and the swelling rate was only 94%, showing excellent water resistance and being able to hold liquids such as water, milk and soy sauce for 24 h. It also showed lower water vapor permeability (615.0 g/(m2·d)) and oxygen permeability (4.15×10-3 cm3/(m2·d·Pa)). This transparent film featured high moisture stability and excellent wet strength, and had good application effect in the fields of packaging and food preservation.
View Full Text  HTML  View/Add Comment  Download reader