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Study on Improving the Durability of Aged Paper Documents by Silicification Modified Bacterial Cellulose/Nano-magnesia Oxide Reinforce Dispersion
Received:January 15, 2025  
DOI:10.11980/j.issn.0254-508X.2025.06.009
Key Words:bacterial cellulose  silylation  nano-magnesium oxide  paper document  durability
Author NameAffiliationPostcode
MOU Hongyan* School of Light Industry and Engineering, State Key Lab of Advanced Papermaking and Paper-based Materials, South China University of Technology, Guangzhou, Guangdong Province, 510640 510640
ZHANG Boer School of Light Industry and Engineering, State Key Lab of Advanced Papermaking and Paper-based Materials, South China University of Technology, Guangzhou, Guangdong Province, 510640 510640
ZHANG Hongjie China National Pulp and Paper Research Institute Co., Ltd., Beijing, 100102
National Engineering Lab for Pulp and Paper, Beijing, 100102 
100102
WU Xiao School of Light Industry and Engineering, State Key Lab of Advanced Papermaking and Paper-based Materials, South China University of Technology, Guangzhou, Guangdong Province, 510640 510640
WU Ting School of Light Industry and Engineering, State Key Lab of Advanced Papermaking and Paper-based Materials, South China University of Technology, Guangzhou, Guangdong Province, 510640 510640
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Abstract:Bacterial cellulose (BC) was used as the reinforcing substrate, chemically modified by 3-aminopropyltriethoxysilane (APTES) and compounded with nano-magnesium oxide (MgO) to produce silanized bacterial cellulose/nano-magnesium oxide (APTES-BC/MgO) reinforce dispersion, which were applied in the study of the durability of reinforced paper. The mechanical properties of APTES-BC/MgO reinforced paper were always higher than those of the BC reinforced paper and the unreinforced paper during the wet-heat aging process. After 30 days of hygrothermal aging test, the transverse tearing index and transverse tensile index of APTES-BC/MgO reinforced paper were still 29.6% and 27.1% higher than those of the unreinforced paper, and the pH value and alkali reserves were 7.56 and 0.25 mol/kg, respectively, with the least whiteness change and colour difference. The aged paper reinforced by APTES-BC/MgO exhibited the excellent durability.
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