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Research on the Removal of Lignin from Corn Stalk Hydrolysate Using Thermal Coagulation of Soymilk
Received:January 25, 2025  
DOI:10.11980/j.issn.0254-508X.2025.06.008
Key Words:corn stalk hydrolysate  biodegradability  soymilk  flocculation process
Author NameAffiliationPostcode
YANG Yuxin* Tianjin Key Lab of Pulp and Paper Industry, Tianjin University of Science and Technology, Tianjin, 300457 300457
QI Jian Tianjin Port Xingyang Machinery Co., Ltd., Tianjin, 300452 300452
LYU Pengjing Tianjin Key Lab of Pulp and Paper Industry, Tianjin University of Science and Technology, Tianjin, 300457 300457
CHEN Yanbing Tianjin Key Lab of Pulp and Paper Industry, Tianjin University of Science and Technology, Tianjin, 300457 300457
SUN Yuru Tianjin Key Lab of Pulp and Paper Industry, Tianjin University of Science and Technology, Tianjin, 300457 300457
DU Peiqing Tianjin Port Xingyang Machinery Co., Ltd., Tianjin, 300452 300452
HUANG Jinda Tianjin Port Xingyang Machinery Co., Ltd., Tianjin, 300452 300452
CHEN Yan Beijing Keyin Media and Culture Co., Ltd., Beijing, 100036 100036
ZHU Yong Sinolight Paper Inspection and Certification Co., Ltd., Beijing, 100102 100102
LIU Chunlan Shandong Kemai Bio-mechanical Pulp Co., Ltd., Weifang, Shandong Province, 262400 262400
LI Min Zhuhai Hongta Renheng Packaging Co., Ltd., Zhuhai, Guangdong Province, 519000 519000
YU Menghui* Tianjin Key Lab of Pulp and Paper Industry, Tianjin University of Science and Technology, Tianjin, 300457 300457
WANG Gaosheng Tianjin Key Lab of Pulp and Paper Industry, Tianjin University of Science and Technology, Tianjin, 300457 300457
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Abstract:This study investigated the impact of high-temperature thermal soymilk (Soymilk-TC) flocculation process on lignin removal from corn stalk hydrolysate and elucidated its reaction mechanism, aming to enhance the biochemical characteristics of the hydrolysate. The results showed that the Soymilk-TC flocculation process effectively removed 85.38% of colloidal lignin and 28.14% of dissolved lignin from the hydrolysate, outperforming the Cationic polyacrylamide and Polyaluminium chloride coagulation methods. By analyzing the chemical structure, surface charge, surface hydrophobicity, free thiol content, etc. of soymilk before and after heat treatment, the thermodynamic changed of protein and lignin and the self-flocculation process of protein in the Soymilk-TC flocculation process were quantitatively analyzed. The results showed that high temperature causes denaturation of soy protein in soymilk and enhanced the surface hydrophobicity of soymilk. It promoted the combination of soymilk and lignin through hydrophobic reaction. Meanwhile, the thiol-disulfide bond reaction promoted the formation of macromolecular aggregates of soymilk molecules combined with lignin, facilitating their separation from the hydrolysate of corn stalks. The biodegradability of the hydrolysate was significantly enhanced by the Soymilk-TC flocculation process, resulting in increases of 207.65% in biogas yield and 34.32% in biogas production rate.
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