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Study on the Effects of Cationic Starch/Nanocellulose Composite System Sizing on the Properties of Paper
Received:September 14, 2024  
DOI:10.11980/j.issn.0254-508X.2024.12.007
Key Words:nanocellulose  cationic starch  food packaging paper  mechanical properties  barrier properties
Author NameAffiliationPostcode
KUI Minghong* Guangdong Guanhao High-tech Co.Ltd. Zhanjiang Guangdong Province524072
Guangdong Guanhow New Materials R&D Co. Ltd. GuangzhouGuangdong Province511400 
511400
WEN Hui Guangdong Guanhao High-tech Co.Ltd. Zhanjiang Guangdong Province524072
Guangdong Guanhow New Materials R&D Co. Ltd. GuangzhouGuangdong Province511400 
511400
MA Hongsheng Guangdong Guanhow New Materials R&D Co. Ltd. GuangzhouGuangdong Province511400
Zhuhai Hongta Renheng Packaging Co. Ltd. ZhuhaiGuangdong Province519000 
519000
WANG Bin School of Light Industry and Engineering South China University of Technology GuangzhouGuangdong Province510640 510640
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Abstract:Cationic starch (CS) and nanocellulose (NC) were used to construct an CS/NC composite system to explore its application value in food soft packaging materials. In this study, softwood pulp and hardwood pulp with beating degrees of 24 and 36 °SR, respectively, were selected as base paper raw materials. A systematic study was conducted on the effects of intra-slurry/surface sizing the CS/NC composite system on the properties of paper. When the CS/NC composite system was applied in intra-slurry sizing, CS was added at a mass fraction of 1.0% (relative to the oven dry fiber weight, hereafter) with cellulose nanofibers (J-CNF) of 0.6%, the tensile index and tearing index of the handmade sheet reached 68.6 N·m/g and 7.79 mN·m²/g, respectively, representing increases of 14.1% and 18.8% compared to the base paper. When the CS/NC composite system was applied in surface sizing, the air permeability of sized paper decreased by 99.4% at cement solid content 6.5%, with a mass ratio cellulose nanocrystal (J-CNC) to CS of 1∶9. Additionally, when the amount of single-sided sizing was 6 g/m², the oil-proof grade of sized paper achieved grade 12.
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