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3D Printed Preparation and Properties of Carbon Nanotube/Nanocellulose Composite Electrode
Received:January 12, 2024  
DOI:10.11980/j.issn.0254-508X.2024.03.001
Key Words:light-curable  3D printing  nanocellulose  carbon nanotube  electrode material
Fund Project:国家自然科学基金(22078187):热-力耦合作用下合成纤维纸多孔结构内纤维形变行为研究;生物质化学与材料国际联合研究中心(2018GHJD-19);陕西省重点产业创新链项目(2020ZDLGY11-03)。
Author NameAffiliationPostcode
ZHANG Sufeng College of Bioresources Chemical and Materials Engineering Shaanxi University of Science & Technology Xi’an Shaanxi Province 710021 710021
WANG Xiaoyi College of Bioresources Chemical and Materials Engineering Shaanxi University of Science & Technology Xi’an Shaanxi Province 710021 710021
LIU Yali College of Bioresources Chemical and Materials Engineering Shaanxi University of Science & Technology Xi’an Shaanxi Province 710021 710021
HE Xinning College of Bioresources Chemical and Materials Engineering Shaanxi University of Science & Technology Xi’an Shaanxi Province 710021 710021
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Abstract:This study explored a visible light-based 3D printing technology for the fabrication of conductive polymer resin materials. A mixture of light-curable resin and multi-walled carbon nanotube (MWCNT) was used as the substrate, and the dispersibility of MWCNT was improved by adding nanocelluloses (CNF) to achieve the best electrical conductivity and printing quality of the hybrid resin. In addition, light curing, pyrolysis, and chemical activation were combined to form carbon electrodes with designable hierarchical pore structures. The electrodes had pore structures with a distribution from millimeter to micron to nanometer scale, and assembled symmetric supercapacitors were provided a high energy density of 0.91 mWh/cm2.
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