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Research Advances in Non-enzymatic Conversion of Carbohydrates to Lactic Acid and Lactate |
Received:December 14, 2022 |
DOI:10.11980/j.issn.0254-508X.2023.04.014 |
Key Words:carbohydrates non-enzymatic catalysis lactic acid lactates Lewis acid Brønsted acid |
Fund Project:国家自然科学基金(31870559;31901262;32071716);福建省杰出青年科学基金(2021J06017);国家林业和草原局科技创新青年拔尖人才项目(20201326005);南京林业大学,江苏省制浆造纸科学与技术重点实验室开放基金(KL201911);福建农林大学杰出青年科学基金(xjq201923)。 |
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Abstract:In this paper, it was summarized that the main-reaction (for example hydrolysis, isomerization, retro-aldol, and hydride shift, etc.) and side-reaction (for example dehydration and condensation, etc.) pathways involved in the catalytic conversion of carbohydrates (three-carbon, five-carbon, six-carbon sugars, and cellulose) to lactic acid/lactates by Lewis acid (L acid) and Brønsted acid (B acid) in conventional catalytic systems (homogeneous and heterogeneous), and corresponding relationships between structure of different catalysts and their catalytic efficiencies. Based on the materials of metal-organic framework (MOF), tin-based silicates and graphitized carbon nitride, the latest research progress in constructing new heterogeneous and photocatalytic systems were reviewed. The future development trend of multifunctional catalysts (including L acid, B acid, binding groups, and multi-level pore structure) was prospected. |
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