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| Preparation and Properties Characterization of Thin-layer Deinking Paper Sludge-based Activated Carbon with a High Mesopore Ratio |
| Received:December 02, 2021 |
| DOI:10.11980/j.issn.0254-508X.2022.05.002 |
| Key Words:deinking sludge KOH deashing ball mill activated carbon |
| Fund Project:泰山学者工程。 |
| Author Name | Affiliation | Postcode | | DAI Yuzhuo | State Key Lab of Bio-based Materials and Green Papermaking, Qilu University of Technology (Shandong Academy of Sciences), Ji’nan,Shandong Province,250353 | 250353 | | JI Xingxiang | State Key Lab of Bio-based Materials and Green Papermaking, Qilu University of Technology (Shandong Academy of Sciences), Ji’nan,Shandong Province,250353 | 250353 | | TIAN Zhongjian* | State Key Lab of Bio-based Materials and Green Papermaking, Qilu University of Technology (Shandong Academy of Sciences), Ji’nan,Shandong Province,250353 Department of Bioengineering, Qilu University of Technology (Shandong Academy of Sciences), Ji’nan,Shandong Province,250353 | 250353 | | MA Hao | State Key Lab of Bio-based Materials and Green Papermaking, Qilu University of Technology (Shandong Academy of Sciences), Ji’nan,Shandong Province,250353 | 250353 | | ZHANG Fengshan | Shandong Huatai Paper Co., Ltd., Dongying, Shandong Province,257335 | 257335 | | FANG Guigan | Institute of Chemical Industry of Forest Products, CAF ,Nanjing, Jiangsu Province,210042 | 210042 |
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| Abstract:The preparation of deinking paper sludge-based activated carbon (DPS-AC) with a thin-layer and high mesopores ratio structure by using deinking paper sludge (DPS) as raw material, via twice deashing with hot water and hydrochloric acid pickling, KOH activation, and ball milling assistance was discussed in this study. The results showed that the optimal process conditions for the preparation of DPS-AC were that hot water pretreatment and acid washing treatment for two deashing, KOH solution concentration of 6.5 mol/L, solid-liquid ratio of 1∶2, carbonization temperature of 750℃, time of 90 min, and 250 r/min intermittent ball milling for 180 min. The DPS-AC prepared under these conditions had an iodine adsorption capacity of 657.50 mg/g, a methylene blue adsorption capacity of 230.69 mg/g, a specific surface area of 595.138 m2/g, a total pore volume of 0.646 cm3/g, an average pore diameter of 4.339 nm, and mesoporous well-developed structure. |
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