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Clean Preparation and Functional Application Prospect of Nanocellulose Based on Formic Acid Hydrolysis
Received:August 15, 2021  
DOI:10.11980/j.issn.0254-508X.2021.11.009
Key Words:nanocellulose  cellulose nanocrystal  cellulose nanofibril  formic acid hydrolysis  clean preparation
Fund Project:国家自然科学基金(31870568);山东省自然科学杰出青年基金(ZR2019JQ10)。
Author NameAffiliationPostcode
DU Haishun CAS Key Lab of Biofuels Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of Sciences Qingdao Shandong Province 266101
Department of Chemical Engineering Auburn University Alabama 36849 USA 
36849
LI Bin* CAS Key Lab of Biofuels Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of Sciences Qingdao Shandong Province 266101 266101
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Abstract:Nanocellulose (NC) is a green and renewable bio-based nanomaterial, and it has been paid widely attentions by academia and industry due to its unique physical and chemical properties. Therefore, clean and effective production of NC is of vital importance for its large-scale production and commercial application. Compared to conventional inorganic acid hydrolysis for the preparation of NC, the advantages of formic acid (FA) hydrolysis method including the whole process for the preparation of NC is clean because FA can be easily recovered and reused. FA can not only hydrolyze cellulose, but also can react with hydroxyls on the surface of cellulose, thus introducing ester groups on NC and achieving simultaneous production and surface modification of NC. Tailored production of NC can be achieved by adjusting the conditions of FA hydrolysis. In addition, the functional applications and prospects of NC prepared by FA hydrolysis are summarized. Due to its unique surface properties, NC prepared by formic acid hydrolysis has broad application prospects in the fields of heterogeneous membrane devices, Pickering emulsions, nanofillers for rubber and plastic composite materials, and so forth.
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