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Preparation and Characterization of Carbon Paper with High Conductivity and High Thermal Conductivity |
Received:May 05, 2019 |
DOI:10.11980/j.issn.0254-508X.2019.07.004 |
Key Words:mesophase pitch-based carbon fiber high electrical conductivity high thermal conductivity carbon paper carban fiber |
Fund Project:本课题由国家重点研发计划项目资助
2017YFB0308200
本课题由国家重点研发计划项目资助(编号:2017YFB0308200)。 |
Author Name | Affiliation | Postcode | WANG Yali | School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin, 300387 | 300387 | HU Rongrong | School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin, 300387 | 300387 | HUA Feiguo | Zhejiang Jinchang Special Paper Co., Ltd., Quzhou, Zhejiang Province, 324400 | 324400 | TONG Shuhua | Zhejiang Jinchang Special Paper Co., Ltd., Quzhou, Zhejiang Province, 324400 | 324400 | XU Yue | China National Pulp and Paper Research Institute Co., Ltd., Beijing, 100102) (* ) | 100102 | MA Chang | School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin, 300387 | 300387 | SHI Jingli | School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin, 300387 | 300387 |
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Abstract:In order to improve the electrical conductivity and thermal conductivity of the carbon paper, the mesophase pitch-based carbon fibers with small electrical resistance and high thermal conductivity were used as a raw material to replace partially the polyacrylonitrile-based carbon fiber to prepare carbon paper. The effects of the proportion of mesophase pitch-based carbon fibers on the morphology, crystal structure, electrical conductivity and thermal conductivity of carbon paper were investigated. The results indicated that with the increase of the proportion of mesophase pitch-based carbon fiber, the degree of graphitization of carbon paper improved obviously, and the electrical conductivity and thermal conductivity increased significantly. When the mass ratio of mesophase pitch-based carbon fiber to polyacrylonitrile-based carbon fiber was 3:7, the degree of graphitization of graphitized carbon paper was 97.4%, its electrical resistivity decreased by 35.7% from 6.80 mΩ·cm to 4.37 mΩ·cm and the vertical surface thermal conductivity increased by 88.8% from 0.084 W/(m·K) to 0.159 W/(m·K) compared with graphitized pure polyacrylonitrile-based carbon paper. |
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