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Study on Fiber Modification of Bleached Masson Pine by Endo-cellulase and Its Mechanism
  
DOI:10.11980/j.issn.0254-508X.2015.03.003
Key Words:endo-cellulase  cellulose microfibril  fiber morphology  crystallinity  fiber properties
Author NameAffiliation
王 转1 1.陕西科技大学轻工与能源学院,陕西省造纸技术及特种纸品开发重点实验室 陕西西安710021 
李新平1 1.陕西科技大学轻工与能源学院,陕西省造纸技术及特种纸品开发重点实验室 陕西西安710021 
杜 敏1 1.陕西科技大学轻工与能源学院,陕西省造纸技术及特种纸品开发重点实验室 陕西西安710021 
王志杰1 1.陕西科技大学轻工与能源学院,陕西省造纸技术及特种纸品开发重点实验室 陕西西安710021 
陈立红2 2.陕西科技大学化学与化工学院陕西西安710021 
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Abstract:The effect of endo-cellulase hydrolysis on fiber morphology,cellulose aggregation structure and fiber properties of bleached masson pine was investigated. The results showed that endo-cellulase preferentially reacted with the fines on fiber surface. Peeling was not very obvious, but cutting effect was significant. With the increasing of dosage, average fiber length, water retention value and absolute value of Zeta potential decreased gradually and the width changed by contraries. The beating degree decreased at first and then gradually increased. Hydrolysis mainly occurred at the amorphous region, so the crystallinity increased and finally fluctuated between 80%~82%. The fiber could be hydrolysed completely only under the synergistic effect of endo-cellulase, exo-cellulase and cellobiase.
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