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Determination of Volatile Organic Compounds in Wallpaper by Environmental Test Chamber-Auto Thermal Desorption- Gas Chromatography/Mass Spectrum Method
  
DOI:10.11980/j.issn.0254-508X.2014.02.006
Key Words:wallpaper  volatile organic compounds (VOCs)  test chamber  auto desorption  mass spectrum
Fund Project:江苏出入境检验检疫局科研项目(2013KJ09)。
Author NameAffiliation
朱海欧 江苏出入境检验检疫局江苏南京210001 
陈 进 江苏出入境检验检疫局江苏南京210001 
卢志刚 江苏出入境检验检疫局江苏南京210001 
李 翔 江苏出入境检验检疫局江苏南京210001 
张 彰 江苏出入境检验检疫局江苏南京210001 
张桂珍 江苏出入境检验检疫局江苏南京210001 
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Abstract:A variety of volatile organic compounds (VOCs) released from different wallpapers, were determined by virtue of 1 m3 environment test chamber, auto thermal desorption (ATD) and gas chromatography/mass spectrum (GC/MS). The study on ATD experimental conditions and adsorbent selection was found that, Carbopack B/CarbosieveTM S-III adsorbent exhibited a better trap performance than conventional Tenax TA, and more suitable for the adsorption of various organic monomer. In this method, the limit ranges of detection (LODs) for various VOCs was 0.01~0.4 μg/m3. The average recovery ranged from 90% to 109%, and the relative standard deviation (RSD) was less than 11%. Test results of various commercially available wallpaper samples showed that the wallpaper material had a great effect on its released VOC composition. Paper base wallpapers emited little TVOC and released just 1-butyl alcohol and propylene glycol, whereas Non-woven wallpapers and PVC wallpapers released more toluene, styrene and 2-ethyl-1-hexanol, nonanal, naphthalene, etc. Much alkanes (straight-chained and branched-chain) were found from metal wall papers.
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