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A New Kinetics Model of Oxygen Delignification of Fast-growing Eucalyptus Kraft Pulp
  
DOI:10.11980/j.issn.0254-508X.2012.06.001
Key Words:oxygen delignification  residual alkali  kappa number  kinetics model
Fund Project:本课题为国家自然科学基金(21076091)资助项目。
Author NameAffiliation
张春云 华南理工大学制浆造纸工程国家重点实验室广东广州510640 
胡会超 华南理工大学制浆造纸工程国家重点实验室广东广州510640 
柴欣生 华南理工大学制浆造纸工程国家重点实验室广东广州510640 
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Abstract:The effects of temperature, oxygen pressure, sodium hydroxide charge and reaction time on oxygen delignification of the fast-growing eucalyptus kraft pulp were investigated. It was found that the concentration of sodium hydroxide during oxygen delignification had a linear relationship with the natural logarithm of kappa number that standing for the residual lignin content in the pulp. Based on the information from the above investigation and observation, a new kinetics model of oxygen delignification was developed. The results showed that the present model could provide a good description for the oxygen delignification of the eucalyptus kraft pulps at different process conditions (R2=0.980). Compared to the traditional kinetics models of oxygen delignification, the present model minimized the number of kinetics parameters in the mathematical equation, which made the model much simpler and reliable.
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