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Study of Binder Migration Mechanism during Consolidation of Coating Suspensions: When Does Migration of Particulate Latex Occur
  
DOI:10.11980/j.issn.0254-508X.2011.04.001
Key Words:consolidation of coating suspensions  binder  migration time  XPS  surface elemental composition
Author NameAffiliation
臧永华1 1.天津科技大学材料科学与化学工程学院天津市制浆造纸重点实验室天津300457 
杜艳芬1 1.天津科技大学材料科学与化学工程学院天津市制浆造纸重点实验室天津300457 
杜 娟1 1.天津科技大学材料科学与化学工程学院天津市制浆造纸重点实验室天津300457 
李 洒1 1.天津科技大学材料科学与化学工程学院天津市制浆造纸重点实验室天津300457 
吴振娟1 1.天津科技大学材料科学与化学工程学院天津市制浆造纸重点实验室天津300457 
程少玲2 2.天津科技大学理学院天津300457 
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Abstract:Surface elemental compositions of model clay/latex coatings consolidated under various conditions were measured using XPS technique, in order to elucidate the moment when the migration of particulate latex relative to pigments during drying of colloidal suspensions takes place. The results showed that surface carbon content was higher for coatings dried at a higher temperature, and surface carbon content reduced greatly as delaying drying at room temperature. The observations provided evidence that latex migration mainly took place after coating application but before capillary formation, i.e., when the coatings were in liquid phase.
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