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Modification of Hydroxymethyl Lignin and the Effect the Product on Paper Strength
  
DOI:10.11980/j.issn.0254-508X.2011.02.017
Key Words:hydroxymethyl lignin  acrylamide  graft copolymerization  paper strengthening agent  FT-IR
Fund Project:本课题得到陕西省“13115”科技创新工程重大科技专项(2008ZDKG-43)资助。
Author NameAffiliation
张美云 陕西科技大学陕西省造纸技术及特种纸品开发重点实验室陕西西安710021 
曹建武 陕西科技大学陕西省造纸技术及特种纸品开发重点实验室陕西西安710021 
李金宝 陕西科技大学陕西省造纸技术及特种纸品开发重点实验室陕西西安710021 
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Abstract:Graft copolymerization of hydroxymethyl lignin and acrylamide with H2O2-Fe(Ⅱ) as initiator was studied. The effects of dosages of acrylamide and initiator, reaction temperature, reaction time on grafting ratio were investigated. The structure of copolymer was analyzed by FT-IR and the copolymer was added into pulp to study its effect on resultant paper properties. The optimum process parameters of the grafting reaction were as follows: the mass ratio of acrylamide to hydroxymethyl lignin is 1.5, the mass ratio of initiator to hydroxymethyl lignin is 0.06, the reaction temperature and time are 60℃ and 3 h respectively.
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