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阳离子淀粉作为固色剂对纸张固色效果的研究
Effect of Cationic Starch as Dye Fixing Agent on Color Fixation on Paper Surface
收稿日期:2018-10-01  
DOI:10.11980/j.issn.0254-508X.2019.03.005
关键词:  固色剂  阳离子淀粉  取代度  固色效果
Key Words:fixing agent  cationic starch  substitution degree  fixing effect
基金项目:基金项目:国家重点研发计划(2017YFB0307900)。
作者单位
陈通1 1. 华南理工大学制浆造纸工程国家重点实验室广东广州510640 
盛杰1 1. 华南理工大学制浆造纸工程国家重点实验室广东广州510640 
韩继友2 2. 民丰特种纸股份有限公司浙江嘉兴314000 
王平军2 2. 民丰特种纸股份有限公司浙江嘉兴314000 
周晓明1 1. 华南理工大学制浆造纸工程国家重点实验室广东广州510640 
杨仁党1,* 1. 华南理工大学制浆造纸工程国家重点实验室广东广州510640 
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摘要:为了改善食用色素中的靓蓝色素在纸张上的固色效果,在浆外染色过程中添加阳离子淀粉,探究了阳离子淀粉在纸张表面固色的机理,以及不同取代度阳离子淀粉的固色效果,并确定了最优固色工艺。采用单因素实验探究了阳离子淀粉的取代度、染液pH值、染液温度、阳离子淀粉用量对纸张固色效果的影响。通过光学显微镜、扫描电子显微镜观测结果推测出带负电的靓蓝色素与带正电的阳离子淀粉相互吸引而紧密结合,携带着靓蓝色素的阳离子淀粉,再与显负电的纤维紧密结合,使颜色稳定固着于纸上。结果表明,取代度越高的阳离子淀粉作为靓蓝色素固色剂的效果越好,即取代度为0.06的阳离子淀粉固色效果最好,最佳固色条件为:染液pH值6,染液温度80℃,阳离子淀粉用量1.5%,较不添加固色剂的空白组固色效果提升84.4%。
Abstract:In order to improve the effect of color fixation on paper, the cationic starch was added in paper dyeing process. In this paper, the mechanism of color fixation on paper surface by cationic starch, the effects of substitution degrees with different cationic starchs and the most optimal fixation technique were studied. Single factor experiments, such as the effects of cationic starch substitution degree, dosage of cationic starch, dye solution pH value and temperature on color fixation efficiency were carried out. It was inferred by optical microscope and SEM observation that due to the close attraction of the negatively charged edible pigments and the positively charged cationic starch. In turn the cationic starch which carries the edible pigment was closely combined with the negatively charged fibers, making the color was fixed on paper. The experiment showed that the higher substitution degree of cationic starch was, the better fixing effect would be. What’s more, the best conditions for color fixation were found as follows: pH value 6, temperature was 80℃, cationic starch dosage was 1.5%, the color fixation effect upgraded 84.4% compared with the blank group.
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