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活性炭负载TiO2的制备及催化臭氧处理造纸废水的应用
Preparation of Activated Carbon Supported TiO2 and Its Application in Catalytic Ozonation Treatment of Papermaking Wastewater
收稿日期：  
DOI：10.11980/j.issn.0254-508X.2011.06.008
关键词:  活性炭负载TiO2  催化氧化  去除率
Key Words:activated carbon supported TiO2  catalytic ozonation  removal rate
基金项目:
作者单位
张贤贤 华南理工大学造纸与污染控制国家工程研究中心，华南理工大学制浆造纸工程国家重点实验室,广东广州，510640 
雷利荣 华南理工大学造纸与污染控制国家工程研究中心，华南理工大学制浆造纸工程国家重点实验室,广东广州，510640 
李友明 华南理工大学造纸与污染控制国家工程研究中心，华南理工大学制浆造纸工程国家重点实验室,广东广州，510640 
马黎明 华南理工大学造纸与污染控制国家工程研究中心，华南理工大学制浆造纸工程国家重点实验室,广东广州，510640 
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摘要:以钛酸丁酯为钛源，用溶胶-凝胶法在活性炭（AC）表面负载TiO2，经焙烧后制得TiO2/AC催化剂，采用X射线衍射（XRD）和扫描电镜（SEM）对TiO2/AC催化剂表面形貌和晶型进行表征，并研究了该催化剂催化臭氧处理造纸废水时对废水CODCr和色度的去除效果。结果表明，TiO2均匀地涂覆于活性炭的表面，经500℃焙烧后的TiO2为钛锐矿晶型，TiO2负载量为3.38%的TiO2/AC催化臭氧处理造纸废水效果最好，当反应12 min时，废水的色度和CODCr去除率达到96.9%和54.4%，分别比单独臭氧化过程提高了12.3和21.7个百分点，比活性炭臭氧化过程提高了5.3和14.2个百分点，TiO2/AC催化臭氧处理造纸废水极大地提高了对废水CODCr的去除率。
Abstract:Activated carbon (AC) supported TiO2 catalysts (TiO2/AC) were prepared by sol-gel method from Ti(OBu)4. The crystalline and morphology of TiO2/AC were characterized by XRD and SEM respectively. The removal rates of CODCr and color of the wastewater during catalytic ozonation with the presence of TiO2/AC were studied. The results indicated that anatase phase was detected after the TiO2/AC was heated at 500℃ for 3 h, and TiO2 particles distributed uniformly on the surface of activated carbon. The best degradation rate during the treatment of papermaking wastewater by TiO2/AC catalytic ozonation process was 3.38% titania loading, color and CODCr removal rates were up to 96.9% and 54.4% respectively when reaction time was 12 min. Which were increased by 12.3 units and 21.7 units compared with that of single ozonation process, and increased by 5.3 units and 14.2 units compared with the activated carbon catalytic ozonation. The CODCr removal rate of papermaking wastewater was greatly increased by TiO2/AC catalytic ozonation.
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