Modification of corn cob residue from xylose production and fabrication of polyurethane foam
投稿时间:2024-03-27  修订日期:2024-04-19
DOI:
Key Words:xylose residue  Xylose residue polyol  polyurethane foam  water  cyclopentane
Fund Project:山东省博士后基金项目(SDCX-ZG-202203006)和齐鲁工业大学校(院)科教产融合试点工程项目(2023PYI008)
作者单位邮编
杨传源 齐鲁工业大学山东省科学院生物基材料与绿色造纸国家重点实验室 250353
梁俊 齐鲁工业大学山东省科学院生物基材料与绿色造纸国家重点实验室 
高帅 齐鲁工业大学山东省科学院生物基材料与绿色造纸国家重点实验室 
李朱霖 齐鲁工业大学山东省科学院生物基材料与绿色造纸国家重点实验室 
赵子金 山东劳动职业技术学院 
王兆江* 齐鲁工业大学山东省科学院生物基材料与绿色造纸国家重点实验室 250353
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Abstract:In this study, xylose residue was used as raw material, polyethylene glycol and glycerol as modifier, liquefaction under specific conditions to prepare xylose residue polyol, water and cyclopentane as blowing agent, and proportionately added catalyst, polyurethane foaming agent and polyisocyanate to prepare polyurethane foam. By exploring the influence of the amount of foaming agent, polyurethane foaming agent and catalyst on the foaming process, the formulation of composite material was developed, and the foam performance was optimized, and the key problem of slow foaming speed of xylose residue polyol was solved. The results showed that the compressive strength reached 257 kPa under aqueous foaming, and 320 kPa under cyclopentane foaming agent. At the same time, adjusting the proportion of catalyst and pH value of polyol significantly increased the foaming speed of polyurethane foam. With the addition of KOH to 60 mg, the foaming time was shortened from 120 s to 50 s, and the foaming time was shortened from 170 s to 90 s. When the amount of KOH increased to 75 mg, the foaming time decreased from 104 s to 52 s, and the foaming time decreased from 101 s to 80 s.
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