Preparation of lignin-based dye adsorption materials and their performance
投稿时间:2024-03-17  修订日期:2024-04-07
DOI:
Key Words:Alkali Lignin  Adsorbent  Methylene Blue  Methyl Orange  Kinetics  Adsorption Isotherm Model
作者单位邮编
温默涵 北京林业大学 100083
徐新 北京林业大学 
李丽君 北京林业大学 
黄剑波 中国制浆造纸研究院有限公司 
张学铭* 北京林业大学 100083
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Abstract:The industrial alkali lignin was subjected to co-activation treatment with ZnCl2, KOH, Urea and carbonization at a high temperature of 700°C, resulting in the production of a lignin-based adsorption material with high adsorption capacity (Zn-LB). The prepared material was then used in adsorption experiments with methylene blue and methyl orange dyes to explore the effects of dye type, adsorption temperature, and a multi-component dye system on the adsorption capacity. The study results indicated that the specific surface area of the prepared Zn-LB samples reached 2190.3 m2/g. The maximum equilibrium adsorption capacities of Zn-LB for methylene blue and methyl orange, as fitted through the Langmuir adsorption isotherm model, were 1345.9 mg/g and 1732.4 mg/g, respectively. Additionally, the adsorption capacity for methylene blue increased with temperature, indicating that the adsorption of methylene blue was an endothermic process; Conversely, the adsorption capacity for methyl orange decreased with rising temperature, suggesting an exothermic process. Therefore, the prepared lignin-based adsorbent material showed excellent application potential in the field of dye wastewater treatment.
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