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Preparation of Carboxymethyl Hemicellulose and Its Application with Polyamide Epichlorohydrin Resin as Wet Strength Additive
Received:September 28, 2018  
DOI:10.11980/j.issn.0254-508X.2019.03.002
Key Words:carboxymethyl hemicellulose  polyamide epichlorohydrin resin  etherification  wet strength
Fund Project:基金项目:广州市科技计划项目(201607020025)。
Author NameAffiliation
SONG Feiyu State Key Lab of Pulp and Paper Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640 
WEI Qi State Key Lab of Pulp and Paper Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640 
MA Hao State Key Lab of Pulp and Paper Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640 
LIU Xiao State Key Lab of Pulp and Paper Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640 
WU Shubin* State Key Lab of Pulp and Paper Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640 
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Abstract:Carboxymethyl hemicellulose (CMX) with high carboxyl content and high molecular weight was prepared by etherification process,and applied with epichlorohydrin resin to improve the wet strength of paper. The preparation conditions were studied such as the alkaline dosage, the alkalization time, the alkalization temperature, the dosage of etherifying agent, the etherification temperature and the etherification time, the optimal preparation process was explored as follows: the alkalization was carried out for 1 h at room temperature after addition of aqueous NaOH, the molar ratio of hemicellulose and NaOH was 1∶2, the etherification was carried out for 5 h and the etherification temperature was 55℃, the molar ratio of hemicellulose and etherification agent was 1∶1. The wet strength index of the paper reached 9.63 N·m/g when CMX and PAE additions were 4.8% and 2.0% respectively , which was 25.8% higher than that of using PAE alone.
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