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A Pulping Black Liquor Treatment Method Including Lignin Separating and Alkali Recovering by Electrolysis
  
DOI:10.11980/j.issn.0254-508X.2019.01.003
Key Words:black liquor  lignin  UASB  reverse osmosis  electrolytic sodium sulfate
Fund Project:广西创新驱动发展专项资金项目(桂科AA17204067);国家自然科学基金项目(21868006)。
Author NameAffiliation
LI Yijing1,2 1.College of Light Industry and Food Engineering Guangxi University Nanning Guangxi Zhuang Autonomous Region 530004
2.Guangxi Key Lab of Clean Pulp & Papermaking and Pollution Control Nanning Guangxi Zhuang Autonomous Region 530004 
NONG Guangzai1,2,* 1.College of Light Industry and Food Engineering Guangxi University Nanning Guangxi Zhuang Autonomous Region 530004
2.Guangxi Key Lab of Clean Pulp & Papermaking and Pollution Control Nanning Guangxi Zhuang Autonomous Region 530004 
XING Deyue1,2 1.College of Light Industry and Food Engineering Guangxi University Nanning Guangxi Zhuang Autonomous Region 530004
2.Guangxi Key Lab of Clean Pulp & Papermaking and Pollution Control Nanning Guangxi Zhuang Autonomous Region 530004 
LI Pengbo1,2 1.College of Light Industry and Food Engineering Guangxi University Nanning Guangxi Zhuang Autonomous Region 530004
2.Guangxi Key Lab of Clean Pulp & Papermaking and Pollution Control Nanning Guangxi Zhuang Autonomous Region 530004 
LI Xusheng1,2 1.College of Light Industry and Food Engineering Guangxi University Nanning Guangxi Zhuang Autonomous Region 530004
2.Guangxi Key Lab of Clean Pulp & Papermaking and Pollution Control Nanning Guangxi Zhuang Autonomous Region 530004 
YIN Yongjun1,2 1.College of Light Industry and Food Engineering Guangxi University Nanning Guangxi Zhuang Autonomous Region 530004
2.Guangxi Key Lab of Clean Pulp & Papermaking and Pollution Control Nanning Guangxi Zhuang Autonomous Region 530004 
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Abstract:Black liquor is always treated by traditional alkali recovery method in which the biomass including lignin is burned to reduce the organic pollutants; and a large amount of CO2 and other harmful gases are generated while generating sodium carbonate. In order to solve this problem, a new method was developed to treat pulping black liquor. The process included five steps: acidified precipitation(A), desalination by frozen crystallization(D), upflow activated sludge bed(UASB), reverse osmosis filtration(RO) and electrolysis(E). The experimental results ware, the yield of lignin was 28.09% of the mass of the black liquid, the alkali production rate was 2.38 g /(h·L), when electrolytic for 24 hours, the alkali recovery rate of sodium sulfate was 50.64%,the electric energy consumption was 1.598 kWh per 1 kg of sodium hydroxide.
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