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苯丙自交联改性无皂乳液表面施胶剂的合成
Synthesis of Modified Self-crosslinking Styrene-acrylic Soap-free Emulsion as Surface Sizing agent
收稿日期:  
DOI:10.11980/j.issn.0254-508X.2011.07.006
关键词:  苯丙乳液  无皂乳液聚合  表面施胶剂  自交联  反应型乳化剂
Key Words:styrene-acrylic soap-free emulsion  surface sizing agent  functional monomers  reactive emulsifier
基金项目:江苏省制浆造纸科学与技术重点实验室开放基金项目(200905)。
作者单位
张 恒1,2 1.青岛科技大学化工学院山东青岛2660422.南京林业大学江苏省制浆造纸科学与技术重点实验室江苏南京210037 
赵娜娜1 1.青岛科技大学化工学院山东青岛266042 
刘丽丽1 1.青岛科技大学化工学院山东青岛266042 
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摘要:采用无皂乳液聚合的方法合成了苯丙乳液表面施胶剂。加入功能性单体双丙酮丙烯酰胺(DAAM)、丙烯酰胺(AM),复配非离子反应型乳化剂KL-100(烯丙氧基壬基酚聚氧乙烯醚硫酸铵)与阴离子反应型乳化剂COPS-1(烯丙氧基羟丙基磺酸钠),并对乳液聚合的工艺参数进行了实验研究,得到最佳反应条件为:硬软单体比例(质量比)1∶1,反应温度75~80℃,乳化剂用量4%,功能性单体用量2%。利用该乳液表面施胶后的纸页具有良好的抗水性和光泽度。
Abstract:The synthesis of styrene-acrylic emulsion by soap-free emulsion polymerization was researched in this paper. Functional monomers, such as diacetone acrylamide (DAAM),acrylamide(AM),and reactive emulsifier formulated by non-ionic reactive surfactant KL-100 and anionic reactive emulsifier COPS-1, were added in the emulsion system. The optimum conditions for emulsion polymerization were obtained: the ratio of hard and soft monomers is 1, reaction temperature 75~80℃, emulsifier dosage 4wt%,and functional monomers dosage 2wt%. Both water resistance and gloss of the paper surface sized by the emulsion were very high.
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