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杨木CTMP碱性H2O2漂白中糖醛酸溶出的研究
Releasing of Uronic Acids in Alkaline Peroxide Bleaching of Aspen CTMP
收稿日期：  
DOI：10.11980/j.issn.0254-508X.2011.06.002
关键词:  杨木CTMP  糖醛酸  碱性H2O2漂白
Key Words:aspen CTMP  uronic acids  alkaline peroxide bleaching
基金项目:国家自然科学基金（30972327）；国家教育部新世纪人才支持计划（NCET-08-0882）项目。
作者单位
霍　丹 山东轻工业学院制浆造纸科学与技术省部共建教育部重点实验室，山东济南，250353 
秦梦华 山东轻工业学院制浆造纸科学与技术省部共建教育部重点实验室，山东济南，250353 
傅英娟 山东轻工业学院制浆造纸科学与技术省部共建教育部重点实验室，山东济南，250353 
徐清华 山东轻工业学院制浆造纸科学与技术省部共建教育部重点实验室，山东济南，250353 
刘　娜 山东轻工业学院制浆造纸科学与技术省部共建教育部重点实验室，山东济南，250353 
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摘要:研究了杨木CTMP碱性H2O2漂白过程中漂白工艺对糖醛酸溶出的影响。结果表明，糖醛酸的溶出主要受体系碱度的影响。高碱度下，H2O2的加入会在一定程度上阻碍糖醛酸的溶出；高温(如高于80℃)会加剧糖醛酸的溶出；一定温度下，糖醛酸的溶出主要在反应初期阶段较快速。正交实验结果表明，影响糖醛酸溶出的漂白工艺条件依次为NaOH用量、温度、H2O2用量、浆浓、反应时间。
Abstract:Some dissolved and colloidal substances (DCS) tend to release during the alkline hydrogen peroxide bleaching of mechanical pulp, and the anionic groups (AGs) in DCS are mainly uronic acids. In this paper, the aspen CTMP were bleached with alkaline hydrogen peroxide under different conditions, and the content of uronic acids in the resultant DCS was determined by spectrophotometric method. The results showed that the amount of uronic acids dissolved was mainly affected by the alkalinity of the system; Peroxide could obstruct the release of the uronic acids under high alkalinity. High reaction temperature (e.g. above 80℃) could result in a significant increase of the content of uronic acids. The results of orthogonal experiments indicated that factors affecting the uronic acids relasase were the dosage of NaOH, temperature, dosage of H2O2, consistency of pulp and reaction time in order.
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