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聚乙二醇改性三聚氰胺甲醛树脂对汽车空气滤纸性能的影响
Influence of Melamine Formaldehyde Resin Modified with Polyethylene Glycol on Performance of Automobile Air Filter Paper
收稿日期:  
DOI:10.11980/j.issn.0254-508X.2011.03.004
关键词:  聚乙二醇  三聚氰胺甲醛树脂  汽车工业空气  滤纸  浸渍树脂
Key Words:polyethylene glycol  melamine formaldehyde resin  filter paper  impregnating resin
基金项目:本课题由东北林业大学研究生科技创新项目及中央高校基本科研业务费专项资金(DL09CB07)资助。
作者单位
唐立生 东北林业大学生物质材料与技术教育部重点实验室黑龙江哈尔滨150040 
刘文波 东北林业大学生物质材料与技术教育部重点实验室黑龙江哈尔滨150040 
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摘要:采用聚乙二醇对三聚氰胺甲醛树脂进行改性,改性后的树脂用作交联剂添加到苯丙乳液中,并对汽车工业滤纸原纸进行浸渍加工处理。通过研究聚乙二醇(P)、三聚氰胺(M)、甲醛(F)的不同配比、树脂添加量及固化pH值,探讨了其作为乳液交联剂对汽车工业空气滤纸的抗张强度、耐破度、耐水性、透气度的影响。实验结果表明,当P与M的摩尔比为0.32,F与M-MP的摩尔比为2.8,改性树脂添加量为苯丙乳液固含量的4%,固化pH值为6 ~ 7时,汽车工业空气滤纸的综合性能最佳(苯丙乳液的上胶量为25%)。当pH值为6时,滤纸的抗张强度为4.51 kN/m,耐破度为340 kPa,耐水性为39.4min,透气度为334 L/(m2·s)。
Abstract:In order to manufacture the automobile air filter paper, the base filter paper was impregnated with styrene-acrylic latex containing the cross-linking agent of melamine formaldehyde resin which was modified with polyethylene glycol (PEG). The influence of various proportion of PEG (P), melamine (M) and formaldehyde (F), resin dose, and curing pH value on tensile strength, burst strength, water-resistance and air permeability of automobile air filter paper were investigated. The result showed that the optimum conditions were as follows: molar ratio of P/M 0.32, molar ratio of F/(M-MP) 2.8, dose of modified resin 4% on styrene-acrylic latex solid content, and curing pH value 6 to 7 (impregnated amount of styrene-acrylic latex 25%). The tensile strength of the filter paper was 4.51 kN/m, burst strength was 340 kPa, water-resistance was 39.4 min, and air permeability was 334 L/(m2·s) when pH value was 6.
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