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木质素/TiO2复合纳米颗粒合成及纳米纤维素基紫外屏蔽膜制备
Preparation of Lignin/TiO2 Nano Composites and Preparation of Nanocellulose-based UV-shielding Film
收稿日期:2021-01-17  
DOI:10.11980/j.issn.0254-508X.2021.05.003
关键词:  木质素  二氧化钛  复合纳米颗粒  紫外屏蔽
Key Words:lignin  titanium dioxide  nano composites  UV-shielding
基金项目:国家重点研发计划(2016YFE0125800);浙江省自然科学基金(LY20C160006)。
作者单位邮编
张金猛 浙江理工大学纺织科学与工程学院(国际丝绸学院)浙江杭州310018 310018
张秀梅 浙江理工大学纺织科学与工程学院(国际丝绸学院)浙江杭州310018 310018
郭大亮 浙江理工大学纺织科学与工程学院(国际丝绸学院)浙江杭州310018
浙江科技学院环境与资源学院浙江杭州310023 
310023
薛国新 浙江理工大学纺织科学与工程学院(国际丝绸学院)浙江杭州310018 310018
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摘要:本研究利用碱木质素作为生物模板诱导剂,通过水热法成功合成了一种具有良好紫外屏蔽性能的木质素/TiO2复合纳米颗粒。结果表明,木质素/TiO2复合纳米颗粒具有锐钛矿晶型、良好的纳米粒径和热稳定性。同时,证实了木质素的含氧官能团和TiO2表面羟基发生类酯化反应,从而使木质素与TiO2形成包覆嵌顿式结构的复合材料。在此基础上,研究了木质素/TiO2复合纳米颗粒与纳米纤维素水凝胶制备薄膜材料的抗紫外性能。结果表明,添加质量分数10% 的木质素/TiO2复合纳米颗粒的纳米纤维素薄膜在全紫外线波段(200 ~ 400 nm)吸收了约90% 的紫外线,表明木质素/TiO2复合纳米颗粒具有良好的紫外屏蔽能力。
Abstract:Alkali lignin was used as a biological template inducer, and lignin/TiO2 UV-shielding nanoparticles were successfully synthesized by hydrothermal method. Comprehensive characterization results showed that lignin/TiO2 composite nanoparticles had anatase crystal form, good nanoparticle size and thermal stability, it also confirmed that the esterification like reaction took place between the oxygen-containing functional groups of lignin and hydroxyl groups on the surface of titanium dioxide. Thus, lignin and titanium dioxide formed a composite material with an incarcerated structure. Besides, the UV-shielding property of the film prepared by lignin/TiO2 nanoparticles and nanocellulose hydrogel was studied. The results showed that the nanocellulose hydrogel composite film with 10% lignin/TiO2 nanoparticles could absorb about 90% UV light at the all band (200~400 nm), indicating that lignin/TiO2 nano composites had a good UV-shielding capability.
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