负载TiO<sub>2</sub>陶瓷纤维与高得率浆混抄对纸张强度和返黄性能的影响

胡嘉驹<sup>1; 2</sup>; 房桂干<sup>1; *</sup>; 李　蔚<sup>2</sup>; 沈葵忠<sup>1</sup>

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负载TiO₂陶瓷纤维与高得率浆混抄对纸张强度和返黄性能的影响

Strength Properties and Yellowing Performances of the Paper Made of High Yield Pulp and Titanium Dioxide Loaded on Ceramic Fiber Matrix

收稿日期：

DOI：10.11980/j.issn.0254-508X.2017.06.002

关键词: 高得率浆陶瓷纤维 TiO2 强度性能返黄

Key Words:high yield pulps ceramic fiber TiO₂ strength properties yellowing

基金项目:中国林科院中央级公益性科研院所基本科研业务费专项资金（CAFYBB2017ZX003-08）；江苏省生物质能源与材料重点实验室项目（JSBEM2014012）。

作者	单位
胡嘉驹^1，2	1.中国林业科学研究院林产化学工业研究所；国家林业局林产化学工程重点开放性实验室；生物质化学利用国家工程实验室；江苏省生物质能源与材料重点实验室,江苏南京，210042；2.华东理工大学材料科学与工程学院,上海，200237
房桂干^1,*	1.中国林业科学研究院林产化学工业研究所；国家林业局林产化学工程重点开放性实验室；生物质化学利用国家工程实验室；江苏省生物质能源与材料重点实验室,江苏南京，210042
李　蔚²	2.华东理工大学材料科学与工程学院,上海，200237
沈葵忠¹	1.中国林业科学研究院林产化学工业研究所；国家林业局林产化学工程重点开放性实验室；生物质化学利用国家工程实验室；江苏省生物质能源与材料重点实验室,江苏南京，210042

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摘要:论文探讨了负载TiO₂陶瓷纤维与高得率浆混抄对纸张强度性能、光学性能和抑制返黄性能的影响。结果表明，陶瓷纤维负载不同尺寸的TiO₂ (普通TiO₂和纳米TiO₂)对纸张性能的影响存在明显差异。相同的无机物加填量时,负载纳米TiO₂陶瓷纤维与高得率浆混抄纸张的抗张强度、耐破强度、撕裂度和层间结合强度等强度性能优于负载普通TiO₂的纸张,但光学性能(白度和不透明度)、抑制返黄性能均不如负载普通TiO₂的纸张。把负载普通TiO₂的陶瓷纤维与高得率浆中进行混抄,可以显著提高纸张的白度、不透明度及抑制返黄性能；当无机物加填量33.8%时,对高得率浆纸张的返黄抑制度达到81.3%(基于PC值的降低)。

Abstract:In this paper, the effects of mixing TiO₂ loaded on ceramic fiber matrix with high yield pulp on the strength, optical properties and the inhibition of brightness reversion resultant paper were studied. It was shown that the properties of the paper containing ordinary TiO₂ were different from that containing nano-TiO₂. At the same inorganic content in the paper, strength properties (tensile strength, burst index, tear index and bonding strength) of the nano-TiO₂ contained paper were all better than that of the TiO₂ contained paper, but its optical properties (brightness and opacity) and yellow-inhibiting properties were lower than that of the TiO₂ contained paper. The optical and yellow-inhibiting properties of the paper could be improved obviously by adding TiO₂loaded on ceramic fiber matrix into the high yield pulps, and a yellow-inhibition of 81.3% (in term of the PC drop) was obtained at inorganic content of 33.8%．

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