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纤维素可控接枝聚合技术的研究进展
Research Progress of Cellulose Controlled Graft Copolymerization Technology
收稿日期:  
DOI:10.11980/j.issn.0254-508X.2013.07.012
关键词:  纤维素  活性-可控自由基接枝聚合技术  氮氧稳定自由基聚合  原子转移自由基聚合  可逆加成-断裂链转移自由基聚合
Key Words:cellulose  active/controlled radical graft polymerization technology  nitroxide-mediated stable free-radical polymerization (NMP)  atom transfer radical polymerization (ATRP)  reversible addition-fragmentation chain transfer polymerization(RAFT)
基金项目:
作者单位
李德娟 齐鲁工业大学制浆造纸科学与技术省部共建教育部重点实验室山东济南250353 
傅英娟* 齐鲁工业大学制浆造纸科学与技术省部共建教育部重点实验室山东济南250353 
秦梦华 齐鲁工业大学制浆造纸科学与技术省部共建教育部重点实验室山东济南250353 
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摘要:介绍了近年来纤维素及其衍生物接枝聚合技术的研究进展及应用,重点介绍了新型的活性-可控自由基接枝聚合技术,包括氮氧稳定自由基聚合(NMP)、原子转移自由基聚合(ATRP)和可逆加成-断裂链转移自由基聚合(RAFT),主要阐述了聚合机理、优缺点和自在纤维素及其衍生物可控接枝聚合改性方面的应用。
Abstract:Cellulose, the most abundant natural polymer, is a kind of renewable and inexhaustible source in the world. Designing the chemical structure of cellulose to creat special functional material is an important way to expand the application area of cellulose. In this paper, the research advance and application of cellulose and cellulose derivatives graft copolymerization technology were reviewed. Cellulose graft copolymerization technology mainly includes the traditional graft copolymerization and new type of active/controlled radical graft copolymerization technology. This paper emphasizes on the active/controlled radical graft copolymerization technology such as NMP、 ATRP and RAFT technology, including their mechanism, corresponding advantages and application in cellulose and cellulose derivatives controlled graft copolymerization.
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