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GC-MS用于测定造纸废水中的多环芳烃 |
The Method of Determining the PAHs in Papermaking Wastewater by GC-MS |
收稿日期: |
DOI:10.11980/j.issn.0254-508X.2012.06.003 |
关键词: 造纸废水 PAHs GC-MS 萃取条件 |
Key Words:papermaking wastewater PAHs GC-MS extraction conditions |
基金项目:本课题得到2011年广东省高层次人才基金项目“BP-模糊智能控制下的造纸废水两相厌氧反应特性研究”资助。 |
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摘要:研究了不同前处理手段和测试条件对气相色谱质谱联用仪(GC-MS)测定造纸废水中多环芳烃(PAHs)持久性有机污染物的影响。经对比,最优测试条件为选用DB-5作为GC-MS毛细管色谱柱,选用二氯甲烷作为萃取剂,萃取时间30 min,同时加入1.0 g NaCl作为盐析剂,机械振荡20 min。 |
Abstract:The effects of different pretreatment methods and test conditions on determination of polycyclic aromatic hydrocarbons (PAHs) in papermaking wastewater by GC-MS were investigated. It was found that the best extracting effects could be obtained by using DB-5 as the chromatographic column of GC-MS, methylene chloride as the extractant, 30 min extraction time, 0.1 g NaCl as salting-out agent, and 20 min mechanical oscillation. Using the optimized conditions the determination results showed that the 6 kinds of PHAs found in the influent leaved only 2 kinds in the effluent. |
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