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<title cf:type="text"><![CDATA[ -->Structural Regulation and Green Process Optimization]]></title>
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<title xmlns:cf="http://www.microsoft.com/schemas/rss/core/2005" cf:type="text"><![CDATA[Construction of Cellulose Films with High Wet-stability Based on Dissolving-co-crosslinking Cellulose in AlCl<sub>3</sub>/ZnCl<sub>2</sub> Aqueous System]]></title>
<link><![CDATA[http://zgzz.ijournals.cn/zgzzen/ch/reader/view_abstract.aspx?file_no=202510007&flag=1]]></link>
<description xmlns:cf="http://www.microsoft.com/schemas/rss/core/2005" cf:type="html"><![CDATA[In this study， AlCl<sub>3</sub>/ZnC<sub>2</sub>/H<sub>2</sub>O was used as solvent， 1，4-butanediol diglycidyl ether (BDDE) was introduced as crosslinking agent， and bleached eucalyptus as the cellulose raw material. Cellulose was dissolved and crosslinked at room temperature to prepare the cellulose film. When the amount of cellulose and BDDE are 1.5% and 1.0%， respectively， the film had the advantages of high strength， high wet stability， high transparency， and biodegradability. Its light transmittance could reach 90%. The stress-strain energies of the obtained cellulose films reached 141.0 MPa and 19.7%， respectively. Even after soaking in water for 24 h， the wet stress and strain could reach 34.7 MPa and 67.3%. After being soaked in water for 7 days， it could still maintain a stable shape， and the swelling rate was only 94%， showing excellent water resistance and being able to hold liquids such as water， milk and soy sauce for 24 h. It also showed lower water vapor permeability (615.0 g/（m<sup>2</sup>·d）) and oxygen permeability (4.15×10<sup>-3</sup> cm<sup>3</sup>/（m<sup>2</sup>·d·Pa）). This transparent film featured high moisture stability and excellent wet strength， and had good application effect in the fields of packaging and food preservation.]]></description>
<pubDate>2025/10/28 19:45:41</pubDate>
<category><![CDATA[Structural Regulation and Green Process Optimization]]></category>
<author><![CDATA[WU Bin,LI Bin,LIANG Tingting,LI Xianchun,LI Xin,WANG Zhiguo]]></author>
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<atom:name>WU Bin,LI Bin,LIANG Tingting,LI Xianchun,LI Xin,WANG Zhiguo</atom:name>
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<title xmlns:cf="http://www.microsoft.com/schemas/rss/core/2005" cf:type="text"><![CDATA[Study on the Effect of Temperature Treatment on the Properties of Cellulose-based Separators]]></title>
<link><![CDATA[http://zgzz.ijournals.cn/zgzzen/ch/reader/view_abstract.aspx?file_no=202510008&flag=1]]></link>
<description xmlns:cf="http://www.microsoft.com/schemas/rss/core/2005" cf:type="html"><![CDATA[In this study， the influence mechanism of temperature treatment on the multi-scale performance of two quantitative cellulose-based separators (E20-L/E40-H) was systematically investigated. The physical properties， mechanical properties， structural evolution， thermal and electrical properties of the separator were comprehensively characterized by medium and high temperature (125 ℃/48 h， 250 ℃/20 min) and low temperature (-40 ℃/48 h， -60 ℃/48 h) treatment. The results showed that extreme low temperature (-60 ℃) increased the liquid absorption rate of E40-H from 104.6% at room temperature to 113.0%， but E20-L decreased from 84.6% at room temperature to 81.3%， and high temperature (250 ℃) significantly reduced the liquid absorption rate of both. 125 ℃ treatment enhanced the mechanical strength through hydrogen bond enhancement (the burst strength of E20-L increased from 81.4 kPa to 86.1 kPa at room temperature， while that of E40-H increased from 96.3 kPa to 105.3 kPa)， and 250 ℃ led to performance degradation due to cellulose degradation. The crystallinity index of E20-L decreased from 71.6% at room temperature to 47.1% at -60 ℃， revealing that the low-quantitative separator was more sensitive to extreme low temperature. Structural analysis confirmed that high temperature destroyed the fiber structure by pyrolysis， which led to fiber collapse， and low temperature induced keratinization. The electrical performance showed an antagonistic law of increasing breakdown voltage at low temperature but increasing ESR and overall deterioration at high temperature.]]></description>
<pubDate>2025/10/28 19:45:42</pubDate>
<category><![CDATA[Structural Regulation and Green Process Optimization]]></category>
<author><![CDATA[ZHANG Liang,LIU Chengyue,LI Nanhua,LI Lizi,KONG Yuling,WU Caiyan,SU Cuiyang,HU Zhijun,CHEN Hua,YOU Yanzhi]]></author>
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<atom:name>ZHANG Liang,LIU Chengyue,LI Nanhua,LI Lizi,KONG Yuling,WU Caiyan,SU Cuiyang,HU Zhijun,CHEN Hua,YOU Yanzhi</atom:name>
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<title xmlns:cf="http://www.microsoft.com/schemas/rss/core/2005" cf:type="text"><![CDATA[<i>In-situ</i> Pore Regulation of Bacterial Cellulose Microgel for High-surfactant-resistant “Island-Chain” Network]]></title>
<link><![CDATA[http://zgzz.ijournals.cn/zgzzen/ch/reader/view_abstract.aspx?file_no=202510009&flag=1]]></link>
<description xmlns:cf="http://www.microsoft.com/schemas/rss/core/2005" cf:type="html"><![CDATA[In this study， hierarchical-pore bacterial cellulose microgels （BC-microgel） were prepared via methods including CaCO₃ content regulation （0~1 200 mg/L）， particle size screening （0.5~100 μm）. Then， AEO/BC-miccrogel/HPMC composite systems were constructed by combining with hydroxypropyl methyl cellulose （HPMC） and fatty alcohol-polyoxyethylene ether （AEO）. The results showed that when the CaCO₃ content was 300 mg/L and the particle size was 15 μm， the microgel structure with an average pore diameter of 3.17 μm could be formed. At this point， the “island-chain” network was stable and the yield stress of the composite system reached 0.89 Pa， and the thixotropic loop area increased to 0.58 Pa/s. Excessive CaCO₃ or improper particle size lead to disorder in pore structure and deterioration of performance. This study elucidated the structure-activity relationship between pore size regulation and network performance， thereby providing a theoretical basis for the functional development of high-concentra-tion surfactant systems.]]></description>
<pubDate>2025/10/28 19:45:43</pubDate>
<category><![CDATA[Structural Regulation and Green Process Optimization]]></category>
<author><![CDATA[SHI Zhiping,WANG Yingchao,LI Kai]]></author>
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<atom:name>SHI Zhiping,WANG Yingchao,LI Kai</atom:name>
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<title xmlns:cf="http://www.microsoft.com/schemas/rss/core/2005" cf:type="text"><![CDATA[Study on the Ameliorative Effect of a Ternary Deep Eutectic Solvent System on Waste Paper Fibers]]></title>
<link><![CDATA[http://zgzz.ijournals.cn/zgzzen/ch/reader/view_abstract.aspx?file_no=202510010&flag=1]]></link>
<description xmlns:cf="http://www.microsoft.com/schemas/rss/core/2005" cf:type="html"><![CDATA[To address the deterioration of fiber quality and mechanical strength degradation during waste paper recycling， this study developed a choline chloride/glycerol/oxalic acid ternary green solvent system for fiber regeneration. Through single-factor experiments， it was found that the optimal processing conditions were as follows： moisture content of wast paper pulp of 10%， pretreatment，<i> </i>temperature of 80 ℃， pretreatment time of 60 min， and solid-liquid ratio of 1∶10. Under these conditions， the tensile index， tear index， and folding endurance of the paper was 15.8 N·m/g， 4.27 mN·m<sup>2</sup>/g and 22 times， respectively. Comprehensive structural characterization analysis showed that the cellulose crystallinity index decreased from 48.5% to 40.8%， accompanied by substantial increases in surface porosity. The above research results indicated that the ternary deep eutectic solvent system exerted an improving effect on waste paper fibers.]]></description>
<pubDate>2025/10/28 19:45:44</pubDate>
<category><![CDATA[Structural Regulation and Green Process Optimization]]></category>
<author><![CDATA[LI Fengfeng,CHEN Xueping,ZHAN Zhengfeng,ZHANG Zhili,WANG Yuanyuan,TONG Guolin]]></author>
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<atom:name>LI Fengfeng,CHEN Xueping,ZHAN Zhengfeng,ZHANG Zhili,WANG Yuanyuan,TONG Guolin</atom:name>
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